Single layer of carbon atoms “torn” out with tape flash graphene

When talking about graphene, we have to first discuss the natural mineral graphite that is commonly existing in our daily life.

As an allotrope of carbon, graphite is a layered product, and the carbon atoms inside graphite are organized layer by layer. Carbon atoms in the same layer “hold hands” and are carefully attached, yet the combination of carbon atoms in between various layers is loose, like a pile of playing cards. With a mild press, the cards will move apart.


(Graphene Powder)

From the point of view of chemical framework, graphite is a transitional crystal in between atomic crystals, metal crystals and molecular crystals. In the crystal, carbon atoms in the same layer form covalent bonds with sp2 hybridization, each carbon atom is linked to three various other carbon atoms, and six carbon atoms create a normal hexagonal ring on the exact same plane, stretching to develop a sheet structure.

If graphite is a pile of playing cards, after that graphene is just one of the cards in this stack of playing cards. Graphene is a two-dimensional material composed of a single layer of carbon atoms. Stacking graphene layer by layer is graphite. A 1 mm thick graphite includes regarding 3 million layers of graphene.

Although graphene exists in nature, it is challenging to peel off a solitary layer framework.

More than two decades ago, Andre Geim and Konstantin Novoselov, researchers at the College of Manchester in the UK, believed that there have to be a way to acquire a solitary layer of graphite.

Exactly how can a solitary layer of graphite be peeled? Researchers took an extremely “straightforward and unrefined” approach – sticking it with tape.

“Similar to when we write a typo on paper, we will stick the typo with tape.” Based on this, researchers strongly connect that if tape can stay with the surface of paper, can it also stay with layers of graphite?


( TRUNNANO Graphenen Powder)

In the experiment, researchers stuck both sides of pyrolytic graphite flakes to an unique tape, and tore off the tape, the graphite sheet was divided into 2. Although the density of graphite currently is still much from that of a single layer of graphite, researchers have confirmed the feasibility of this approach – each time the tape is made use of, the graphite comes to be thinner. By demanding utilizing this “mechanical peeling technique” to repeat the operation, they lastly acquired a slim sheet containing just one layer of carbon atoms, which is graphene.

However, this method of repeatedly exfoliating graphite sheets with tape to obtain graphene has low production performance and can only be utilized to prepare micron-thick graphene, and can not be mass-produced industrially.

Later on, with the improvement of scientific and technical degrees, the prep work technique of graphene has additionally made great progression. Today, in addition to this traditional physical and mechanical exfoliation method, there are also several methods for preparing graphene, such as redox technique, solvent exfoliation technique, chemical vapor deposition, etc

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